(a)Yes,these chambers remain in a state of electrical neutrality as there are same number of positive ions as there are negative ions.
(b)When diffusion starts,as concentration of KCl in chamber A is more than the concentration of KCl in chamber B,so,Cl-moves from Chamber A to Chamber B.This diffusion takes place until they attain equilibrium i.e concentration in Chamber A is equal to concentration in Chamber B.
10×V+100×V=x×2V
10×V+100×V=x×2V
x=110/2=55mM
x=110/2=55mM (Answer)
This is the equilibrium concentration.
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