1. If 1.3 L of 3.0M potassium hydroxide completely neutralizes 0.7 L of carbonic acid
(H2CO3), what is the concentration of the carbonic acid? 2KOH+H,CO, K,CO,+2H₂O
2. How many moles of HCl are present in 0.07 L of 6 M HCI? 3. I add 7 mL of 2 M NaOH to 50 mL of water. What is the new concentration?
Rates of Reactions-Le Chatlier's Principle
2KOH+H₂CO,→K.CO,+2H2O overall energy of reaction (AH)=-683.84 kJ/mol 1. Describe 2 ways you could increase the amount of products of this reaction at
equilibrium. 2. Describe 2 ways you could increase the amount of reactants of the reaction at
equilibrium.
1.
n (KOH)= CM * V = 1,3 * 3 = 3,9 mol
2KOH + H2CO3 = K2CO3 + 2H2O
2mol KOH — 1mol H2CO3
3,9mol KOH — X
X = 3,9 * 1 / 2 = 1,95 mol H2CO3
CM(H2CO3) = n / V = 1,95 / 0,7 = 2,786 mol/l
Answer: 2,786 mol/l H2CO3
2.
n(HCl)= CM * V = 6 * 0,07 = 0,42 mol
Answer: 0,42 mol HCl
3.
CM (old) = 2 mol/l
V (old) = 7 ml = 0,007 l
V (new) = 57 ml = 0,057 l
n(NaOH)= CM * V = 2 * 0,007 = 0,014 mol
CM(new) = n / V(new) = 0,014 / 0,057 = =0,2456 mol/l
Answer: 0,2456 M NaOH
2KOH + H2CO3 = K2CO3 + 2H2O + 683,84 kJ
1.
Increasing the reaction products is to shift the equilibrium of the chemical reaction to the right. For this:
a) Since the reaction is exothermic, it must be cooled.
b) water or K2CO3 should be removed from the reaction.
c) KOH or H2CO3 should be added.
2.
increasing the amount of reactants shifts the equilibrium of this chemical reaction to the left. For this:
a) Since the reaction is exothermic, it must be heating.
b) K2CO3 or H2O should be added.
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