Calculate the pH of 50 ml of 0.1000 M methylamine solution after the following volume of 0.1000 M HNO3, where added 0
n(CH3NH2) = CM * V = 0.1 * 0.05 = 0.005mol
n(HNO3) = CM * V = 0.1 * 0 = 0 mol
CH3NH2 + H2O = CH3NH3+ + OH-
1mol CH3NH2 => 1mol OH-
0.1 M => X = 0.1 M OH-
Methylamine, CH3NH2, is a weak base that reacts with water according to the above equation. For this reaction at equilibrium, Kb = 4.4 x 10-4
CM (OH-) = 0.1 * 4.4*10-4 = 4.4*10-5 M
pOH = -log [OH-] = - log (4.4*10-5) = 4.357
Using pH + pOH = 14, we find the pH value:
pH = 14 - pOH = 14 - 4.357 = 9.643
Answer: pH = 9.643
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