What volume will 200 ml of gas at 20 o C and 800 mm Hg occupy at STP?
Given:
P1 = 800 mmHg
V1 = 200 mL
T1 = 20°C + 273.15 = 293.15 K
P2 = 760 mmHg (STP)
V2 = unknown (STP)
T2 = 0°C + 273.15 = 273.15 K (STP)
Formula: P1V1/T1 = P2V2/T2
Solution:
Combined gas law can be used.
Combined gas law can be expressed as:
P1V1/T1 = P2V2/T2
Cross-multiply to clear the fractions:
P1V1T2 = P2V2T1
Divide to isolate V2:
V2 = (P1V1T2) / (P2T1)
Plug in the numbers and solve for V2:
V2 = (800 mmHg × 200 mL × 273.15 K) / (760 mmHg × 293.15 K) = 196.2 mL
V2 = 196.2 mL
Answer: 196.2 mL
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