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How would you detect the presence of Chloride, Bromide and Iodide in presence of each other?


1h ago


Alan Carifio

Chlorine Dioxide Generation from 3 solutions?


Using a 25% Sodium Chlorite solution with a 15% Sodium Hypochlorite solution and a 31% Muriatic Acid solution (HCL) to generate Chlorine Dioxide. I have 3 different strengths of solutions to produce chlorine dioxide. Do I have to account for the 3 different strengths when I write out my chemical eqaution?

Reaction:

2NaClO2 + NaOCl + 2HCL yields 2ClO2 + 3NaCl + H20 (correct??)

181 mw + 74.5mw + 73 mw yields 125 mw + 175.5 mw

328.5 = 328.5

55% Sodium Chlorite, 23% Chlorine, 22% Muriatic Acid yields 41% C Dioxide, 53% NaCl, 6% H20 (correct)

50 gals of Sodium Chlorite, plus (50x0.23) to get 11.5 gals of Hypo plus(50x0.22) to get 11 gals of HCL to yield 41% of the Chlorine Dioxide gas from the total reaction? Do I have to take in to account the % of each solution? Do I have to adjust the stochiometric equation ?


25% Sodium Chlorite = 10.59 lbs/gal

15% Hypo = 10.42 lbs gal

HCL (muriatic acid) = 9.67 lbs/gal

A

Alan Carifio


Different types of interaction in elements
1. After the discovery of protons and electrons, it was noticed that there was trend in the periodic table. Helium weighs ~4 and is atomic number 2, Carbon weights ~12 and has atomic number 6. Heavier elements can weigh more than double the atomic number (i.e., gold: atomic mass = 197, atomic number = 79, while for hydrogen atomic mass = 1, atomic number = 1.) How can we best explain this deviation in the trend?
9. The difference in ionization energies in carbon is largest between the fourth and fifth ionization. Why do you think this is? A. Carbon likes to form four bonds so it gives up four electrons B. The difference fourth and fifth ionization energies is substantially larger because carbon can only give up four electrons. C. The fifth ionization requires ionizing core electron. D. Carbon likes to form four bonds so it adds four electrons.
7. Based on Coulomb's Law V=keq1q2r how we can make comparison between ionization energy of Rubidium (Rb) and Krypton (Kr)? A. The ionization energy of Rb is larger than Kr, which is consistent with the increase in the charge. B. The ionization energy of Kr is larger than Rb, which would require the size to increase. C. The ionization energy of Kr is larger than Rb, but since both charge and radius are responsible for ionization energy, no certain conclusion about the size can be made. D. The ionization energy of Rb is larger than Kr, which would require the size to decrease.
2. You performed an X-ray spectroscopy experiment and observed the emission from unknown element A to be 21×1016 Hz and the emission from unknown element B to be 71.5×1016 Hz. It is known that X-ray frequency increases with atomic number and fits the quadratic function of Y=X2. If Unknown A is Neon, what is the likely identity of element B? A. Unknown B is Carbon. B. Unknown B is Argon C. Unknown B is Fluore D. Unknown B is Titanium
Concentrated sulphuric acid is a solution that has a density of 1.84g/ml and contains 98.3% H2SO4 by mass.what is the molarity of this acid

1.Calculate the pH of an aqueous solution of a 0.039 M HCI.

2. Calculate the pOH of an aqueous solution of .0.073 M LiOH.

3. The pOH of a solution of NaOH is 11.30. What is the [H*] for this solution?

4. The pH of a 0.02 M solution of an unknown weak acid is 3.7. what is the pKa of this acid?

5. What is the concentration of ammonium chloride in a solution if its pH is 4.80?

6. The pH of a solution is 4.80. What is the concentration of hydroxide ions in this solution?


  1. Calculate the pH of water in a cloud that has equilibrated with SO2(g) at a concentration of 1.0 ppm by volume.
  2. A solution contains 2 mg/L CN- and is at pH 8.5
  • What is the concentration of HCN(aq) in solution?
  • If the partial pressure of HCN(g) above the solution is 10-6 atm, would HCN transfer from the gas phase into solution or from the solution into the gas, or is the system at equilibrium?
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