Assign oxidation numbers to all atoms, tell in each which substance is undergoing oxidation and which reduction
PbO2(s)+ Cl(aq)>PbCl2(s)+ O2(g)
Solution:
PbO2(s) + 2Cl−(aq) → PbCl2(s) + O2(g)
Oxidation half-reaction:
2Cl− − 2e− → Cl20
Reduction half-reaction:
Pb4+ + 2e− → Pb2+
Therefore,
Cl−(aq) undergoes oxidation
PbO2(s) undergoes reduction
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