For the following reaction at 373 K, Kc = 0.50. If the initial concentration of N2O4 is 0.152 M, what is the equilibrium concentration of NO2?
N2O4 (g) ⇆ NO2 (g)
Solution:
Balanced chemical equation:
N2O4(g) ⇆ 2NO2(g)
For the given reaction,
ICE Table:
According to the ICE Table:
[NO2] = 2x
[N2O4] = 0.152 − x
Kc = 0.50
Therefore,
0.50 = (2x)2 / (0.152 − x) = (4x2) / (0.152 − x)
4x2 + 0.50x − 0.076 = 0
Solving this quadratic equation, we get:
x = 0.089
[NO2] = 2x = 2 × 0.089 = 0.178 M
[NO2] = 0.178 M
Answer: The equilibrium concentration of NO2 is 0.178 M
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