The lattice spacing in a typical solid is d = 0.3 nm. Find the temperature
below which the free electrons in a solid are quantum mechanical? (Hint: Refer the
a) part of the question and treat free electrons as a gas and the lattice spacing as the
typical distance between the electrons)
Answer
For free electrons or quantum mechanically system
"T=\\frac{h^2}{3mkd^2}\\\\=\\frac{(6.6\\times10^{-34})^2}{3\\times 9.1\\times10^{-31} 1.4\\times10^{-23} (3 \\times10^{-10} )^2}\\\\=1.3\\times10^{5}K"
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