In solvolysis of alkyl halides, substitution of alkyl groups at the B 'carbon atom increases E1 over SN1.
The factors that influence whether an elimination reaction proceeds through an E1 or E2 reaction are almost exactly the same as the factors that influence the SN1/SN2 pathway. Cation stability, solvents and basicity play prominent roles. However, basicity may be the single most important of these factors
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