What is the [H3O+ ] of 1.0 MÂ HF mixed with 1.0 M NaF. Ka = 6.6 x 10-4
Solution:
The Henderson-Hasselbalch equation is commonly used to calculate the pH of a buffer solution from the concentration of the buffer components:
where pKa is the acid dissociation constant and [base] and [acid] are the base and acid concentrations, respectively.
base = NaF
acid = HF
Therefore,
pH = −log(6.6×10−4) + log(1.0 / 1.0) = 3.18 + 0 = 3.18
pH = 3.18
pH = −log[H3O+]
Therefore,
[H3O+] = 10−pH = 10−3.18 = 6.6×10−4
[H3O+] = 6.6×10−4 M
Answer: [H3O+] = 6.6×10−4 M
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